Chapter 2: Electrostatic Potential and Capacitance
Chapter 1 introduced the vector description of electrostatics — the field E. This chapter develops the scalar description — the electrostatic potential V. Because V is a scalar (one number per point, not three), it is easier to compute, easier to add, and easier to visualize via equipotential surfaces. The two descriptions are connected by E=−∇V.
The chapter then applies these ideas to capacitors — devices that store charge and energy in an electric field. Capacitors are everywhere: camera flashes, defibrillators, computer DRAM, radio tuners.
Concept Map
2.1 Electrostatic potential — definition and sign convention
2.2 Potential due to a point charge — derivation
2.3 Potential due to a system of charges and a dipole
2.4 Equipotential surfaces — properties
2.5 Relation between E and V — gradient form
2.6 Electrostatic potential energy — pair, system, dipole in field
2.7 Conductors in electrostatic equilibrium
2.8 Electrostatic shielding
2.9 Dielectrics — polarization, dielectric constant K
2.10 Capacitors — Q=CV
2.11 Parallel plate capacitor — C=ε0A/d; with dielectric
2.12 Combination of capacitors — series and parallel
2.13 Energy stored — derivation; energy density
2.14 Dielectric inserted with battery (V const) vs disconnected (Q const)
2.1 Electrostatic Potential
Definition
The electrostatic potentialV at a point P is the work done by an external agent (against the electrostatic force) in bringing a unit positive test charge from infinity (the conventional reference) to P, quasi-statically:
V(P)=q0Wext,∞→P.
Equivalently, in terms of the field:
V(P)=−∫∞PE⋅dl.
Units.1 volt=1 J/C. Also V/m for field.
Sign Convention
V>0 near a positive charge (positive work done against the field to bring a positive test charge close).
V<0 near a negative charge.
V(∞)=0 by convention.
Relation to Potential Energy
If a charge q is placed where the potential is V, the potential energy of the charge in this field is
U=qV.
The change in PE moving from A to B is ΔU=q(VB−VA)=−Wfield.
Worked Example
A test charge q0=+1 nC is moved from A to B where VA=100 V and VB=30 V. Work done by the electric field:
Wfield=q0(VA−VB)=(10−9)(70)=7×10−8 J.
The field does positive work moving a + charge from higher to lower potential.
Pitfalls
V is a property of the field/source, defined at every point — the test charge is conceptual only.
The sign of work: Wext=−Wfield=q(VB−VA).
Choice of reference is arbitrary; only differences matter.
2.2 Potential Due to a Point Charge
Definition / Derivation
Bring a unit positive test charge from ∞ to a distance r from a point charge q, along a radial path.
Step 1. Field at distance r′: E=kq/r′2, radially outward (for q>0).
Step 2. Work done by the field when test charge moves from r′ to r′−dr′ (toward q): dWfield=−Edr′⋅(sign of motion). Going from ∞ to r, dl=−dr′ along outward r^, so E⋅dl=E(−dr′):
Inside a conductor in equilibrium, the entire volume is at one potential — the conductor is an equipotential.
Standard Patterns
Point charge: concentric spheres centered on the charge.
Uniform field: parallel planes perpendicular to E.
Dipole: complicated curves — except the equatorial plane, which is the V=0 equipotential.
Worked Example
A uniform field E=100i^ V/m exists in a region. Sketch the equipotentials passing through x=0,1,2,3 m.
V(x)=−∫0xEdx′=−100x (taking V(0)=0). Equipotentials at 0,−100,−200,−300 V are vertical planes spaced 1 m apart.
Pitfalls
Equipotential = equal-field surface. A point at distance r from +q is at the same potential as a point at distance r from −q on the equatorial plane (both zero) — but the fields can be very different.
Equipotentials need not be closed surfaces.
2.5 Relation Between E and V
Derivation
For a small displacement dl, the change in potential is
dV=−E⋅dl=−Eldl,
where El is the component of E along dl.
Step 1. Choosing dl along the direction of fastest decrease of V gives
El=−dldV.
Step 2. In Cartesian form,
E=−∇V=−(∂x∂Vi^+∂y∂Vj^+∂z∂Vk^).
The minus sign: E points from high V to low V.
Worked Example
Given V(x,y,z)=5x2−3y+2z (in volts, x,y,z in meters), find E.
E=−∇V=−(10xi^−3j^+2k^)=−10xi^+3j^−2k^ V/m.
At the origin: E=3j^−2k^ V/m.
Pitfalls
V is constant inside a conductor ⇒E=0 inside (consistent with electrostatic equilibrium).
The minus sign is essential — students often drop it.
For spherically symmetric V(r): E=−(dV/dr)r^.
2.6 Electrostatic Potential Energy
(a) Two Point Charges
The PE of two point charges q1,q2 separated by r is the work done to bring them from infinity to that configuration:
U12=4πε01rq1q2.
Sign: positive for like charges (positive work needed), negative for unlike (energy released).
(b) System of n Charges
Sum over all distinct pairs:
U=4πε01i<j∑rijqiqj.
Worked Example — Three Charges
Charges +q,+q,+q at vertices of an equilateral triangle of side a.
U=3⋅akq2=a3kq2.
For three charges +q,−q,+q at the same vertices:
U=kq2/a−kq2/a−kq2/a=−kq2/a.
(c) Dipole in an External Field
(Derived in 1.8.) With reference U(θ=π/2)=0:
U(θ)=−p⋅E.
(d) Worked Example — Energy released
Take two charges +q and −q from separation 2r to separation r.
ΔU=(−kq2/r)−(−kq2/(2r))=−kq2/(2r). Energy released =+kq2/(2r) (system more bound).
Pitfalls
U is a property of the configuration, not of a single charge.
For pairs, do not double-count: ∑i<j, not ∑i=j.
Sign of U: same-sign charges →U>0; unlike →U<0.
2.7 Conductors in Electrostatic Equilibrium
Definition
A conductor contains free electrons. In electrostatic equilibrium these have rearranged so that no net flow occurs.
Key Properties
E=0 inside the conductor (otherwise free charges would still move).
V is constant throughout the conductor (since E=0⇒∇V=0).
Net charge resides on the outer surface (Gauss's law inside: enclosed charge =0).
E at the surface is perpendicular to the surface (any tangential component would drive currents).
Magnitude at the surface: E=σ/ε0.
Surface charge density is higher where curvature is higher (sharp points → high σ→ corona discharge).
Derivation — E=σ/ε0 just outside
Use a small Gaussian pillbox straddling the surface, faces parallel to the surface.
Field inside conductor: 0. So flux through inner face is 0.
Field outside is perpendicular to surface (property 4). Flux through outer face: EA.
Lateral flux: zero (in the limit of thin box).
Enclosed charge: σA.
Gauss: EA=σA/ε0, so E=σ/ε0.
Worked Example
An isolated conducting sphere of radius R carries charge Q. Find V everywhere.
Outside (r>R): V=kQ/r (behaves like point charge at center).
Surface (r=R): VR=kQ/R.
Inside (r<R): V=VR=kQ/R (constant; field is zero inside).
Pitfalls
V inside is not zero — it's whatever value the surface holds.
Field changes discontinuously at the surface (from 0 inside to σ/ε0 outside) but V is continuous.
2.8 Electrostatic Shielding
Concept
If we hollow out a region inside a conductor (a cavity, with no charges inside), then E=0 throughout the cavity — regardless of charges outside the conductor.
Why? The conductor rearranges its surface charges to ensure E=0 in its bulk; by uniqueness, the field in the cavity must also be zero (Laplace's equation with zero boundary).
Applications
Faraday cage: electronic equipment, MRI rooms, cars during lightning.
Coaxial cables with grounded shielding.
Sensitive instruments shielded by metal enclosures.
Pitfalls
Shielding works only against external electrostatic fields. A charge inside the cavity does produce a field there.
The cage need not be solid metal — a fine mesh works for low-frequency fields (this is electromagnetic shielding territory, but the principle is electrostatic).
2.9 Dielectrics
Definition
A dielectric is an insulator with no (or few) free charges, but whose molecules can be polarized by an external field.
Polar vs Non-polar
Non-polar molecules (e.g., H2,O2): no permanent dipole; an external field separates the positive and negative centers a tiny amount, induced dipole.
Polar molecules (e.g., H2O, HCl): have permanent dipole moment, randomly oriented in absence of field; an external field aligns them partially.
In both cases, the result is a polarizationP — dipole moment per unit volume.
Dielectric Constant
When a dielectric fills a capacitor, the induced polarization reduces the net field. The dielectric constantK (also εr) is:
This is a general result: the electric field carries energy density 21ε0E2 everywhere.
Worked Example
A 10μF capacitor charged to 100 V:
U=21(10×10−6)(100)2=0.05 J=50 mJ.
Pitfalls
The factor of 1/2 comes from the averaging (you start at V=0 and end at V).
When connecting a charged capacitor in parallel with an uncharged one, charge is conserved, but energy is not — some is dissipated as heat/radiation regardless of how slowly you connect them.
2.14 Effect of Inserting a Dielectric
Case 1 — Battery Connected (V constant)
The battery holds V fixed at V0.
Quantity
Before
After (slab K)
V
V0
V0
C
C0
KC0
Q
C0V0
KC0V0
E
V0/d
V0/d
U
21C0V02
21KC0V02
Energy increases; extra energy comes from the battery (battery supplies ΔQ at V0, doing work V0ΔQ=V0(KC0V0−C0V0)=(K−1)C0V02; half goes to extra capacitor energy, half is dissipated).
Case 2 — Battery Disconnected (Q constant)
Quantity
Before
After (slab K)
Q
Q0
Q0
C
C0
KC0
V
Q0/C0
Q0/(KC0)
E
V0/d
V0/(Kd)
U
Q02/(2C0)
Q02/(2KC0)
Energy decreases; work is done by the field on the dielectric as it is drawn in.
Worked Example
A capacitor with C0=1μF is charged to 100 V then disconnected. A slab with K=4 is inserted.
Q0=10−4 C unchanged.
New C=4μF.
New V=25 V.
New U=21(4×10−6)(25)2=1.25×10−3 J (decreased from 5×10−3 J).
Energy lost = 3.75 mJ, done as work on the dielectric (or radiated).
Pitfalls
The two scenarios give opposite changes in energy — read the problem carefully.
E inside the dielectric changes in both cases: in case 1 it stays the same; in case 2 it drops.
Solved Problems
Problem 1 (Easy)
Find the work done in moving a +2μC charge from a point where V=−50 V to a point where V=+200 V.
Wext=qΔV=(2×10−6)(250)=5×10−4 J.
Problem 2 (Easy)
Three capacitors of 1,2,3μF are connected in series across 11 V. Find the charge and voltage across each.
1/C=1+1/2+1/3=11/6⇒C=6/11μF.
Q=CV=(6/11)×11=6μC on each.
V1=6 V,V2=3 V,V3=2 V (sum =11 V).
Problem 3 (Medium)
Two capacitors of C1=3μF (charged to 300 V) and C2=2μF (uncharged) are connected together (positive to positive). Find the common potential and energy loss.
Charge conservation: Q1+Q2=C1⋅300=900μC.
Common potential: V=900/(C1+C2)=900/5=180 V.
Ubefore=21(3×10−6)(300)2=0.135 J.
Uafter=21(5×10−6)(180)2=0.081 J.
ΔU=0.054 J dissipated.
Problem 4 (Medium)
A spherical conductor of radius R1=5 cm, carrying charge Q1=1μC, is connected by a thin wire to another isolated sphere of radius R2=10 cm, initially uncharged. Find the final charges.
When connected, they reach the same potential.
V=kQ1′/R1=kQ2′/R2⇒Q1′/Q2′=R1/R2=1/2.
Q1′+Q2′=1μC.
Q1′=1/3μC, Q2′=2/3μC.
Surface densities: σ1/σ2=(Q1′/4πR12)/(Q2′/4πR22)=(1/3)(R22/R12)/(2/3)=R22/(2R12)=100/(2⋅25)=2. So smaller sphere has higherσ — explains lightning rods.
Problem 5 (Medium)
A parallel plate capacitor of C=5μF, plate separation 4 mm, is connected to 200 V. A dielectric slab of K=4 and thickness 2 mm is inserted (filling half the gap). Find new C, Q, V, U.
Cnew=d−t+t/Kε0A=4−2+0.5ε0A=2.5ε0A (in mm units).
Compared to C0=ε0A/d=ε0A/4: Cnew/C0=4/2.5=1.6. So Cnew=8μF.
If battery is still connected: V=200 V, Q=1.6 mC, U=0.16 J (up from 0.1 J).
Problem 6 (Hard)
A charged isolated soap bubble of radius R at potential V has charge Q=RV/k. If it bursts into a single drop, find the potential of the drop. Assume same total charge, mass conserved (so volume conserved, surface area not).
Soap bubble: treat the surface as a thin spherical shell of charge Q. Inside the bubble (before bursting) the field is zero and potential is V.
When the bubble bursts and collapses into a single drop: the total volume of soap film, 4πR2⋅t, becomes the volume of the drop 34πr3. So r=(3R2t)1/3, very small.
New potential: V′=kQ/r=V⋅R/r=V(R/r), which is much larger than V.
(In some texts the question is "n identical droplets coalesce" — see Edge Cases.)
Problem 7 (Hard)
A capacitor C1=2μF is charged to V0=100 V. It is then connected through a resistor to an uncharged C2=3μF. Find the final charges and total energy dissipated.
Qinitial=200μC.
After connection (equilibrium, same voltage): Vf=200/(C1+C2)=200/5=40 V.
Q1′=80μC, Q2′=120μC.
Ui=21(2×10−6)(100)2=0.01 J=10 mJ.
Uf=21(5×10−6)(40)2=4 mJ.
Energy dissipated = 6 mJ.
(Notably, the energy dissipated does not depend on R.)
JEE/NEET Edge Cases
Energy lost is independent of the resistor when connecting capacitors: dissipation is 2(C1+C2)C1C2(V1−V2)2.
n identical droplets coalesce into a big drop: big drop's radius is n1/3r. Charge =nq. Potential Vbig=k(nq)/(n1/3r)=n2/3Vsmall.
Capacitor with conductor slab of thickness t: C=ε0A/(d−t). The slab can be anywhere between the plates; it does not matter.
Capacitance of an isolated sphere of radius R in vacuum: C=4πε0R (taking V relative to infinity).
Spherical capacitor (inner radius a, outer b): C=4πε0ab/(b−a).
Force between capacitor plates (battery disconnected, charge constant): F=Q2/(2ε0A)=σ2A/(2ε0) — half of what you'd expect from "naively" applying F=qE because each plate sees only the other plate's field, σ/(2ε0), not the full σ/ε0.
Maximum voltage before dielectric breakdown: Vmax=Ebr⋅d. Different dielectrics: air ∼3×106 V/m, mica ∼108 V/m.
Combination of three capacitors at corners of a triangle with one missing edge — often a Wheatstone-bridge-like situation; if balance condition holds, the bridge capacitor carries no charge.
Inside a hollow conductor at potential V0: V=V0 everywhere inside, even if there is a cavity with no charge.
Quick Recap
V(P)=−∫∞PE⋅dl; V=kq/r for point charge.
E=−∇V; perpendicular to equipotentials.
U12=kq1q2/r; Udipole=−p⋅E.
Conductors: E=0 inside, V constant, E=σ/ε0 just outside.
C=Q/V; parallel plate C0=ε0A/d.
Series: 1/Ceq=∑1/Ci. Parallel: Ceq=∑Ci.
U=21CV2=21Q2/C; energy density u=21ε0E2.
Dielectric (battery connected): V const, Q and U rise by K.
Dielectric (disconnected): Q const, V and U drop by K.
Class XII Ch 2 — Electrostatic Potential and Capacitance
15 questions · pick the best answer
Q1
The electric potential at a point at distance r from a point charge q varies as:
Q2
The work done in moving a +1μC charge from a point at −20 V to a point at +30 V is:
Q3
Equipotential surfaces of a single point charge are:
Q4
Three capacitors 2,3,6μF are connected in series. The equivalent capacitance is:
Q5
A parallel plate capacitor has C0 in vacuum. When the gap is fully filled with a dielectric of constant K:
Q6
A capacitor is charged by a battery and then the battery is disconnected. A dielectric slab is then inserted. Which quantity remains unchanged?
Q7
The energy stored in a 2μF capacitor charged to 100 V is:
Q8
The relation between electric field and potential in one dimension is:
Q9
Inside a charged hollow conducting sphere, the electric field is zero. The potential is:
Q10
Two charged spheres of radii R1 and R2 (with R1<R2) are connected by a wire. After equilibrium, the surface charge densities satisfy:
Q11
When two capacitors of capacitances C1 and C2 charged to voltages V1 and V2 are connected in parallel (positive to positive), the loss of energy is:
Q12
The dipole potential at a general point at distance r≫a from a dipole of moment p, at angle θ from the axis, is:
Q13
Two capacitors of 4μF each are first connected in series, then in parallel, across a 10 V supply. The ratio of total charges drawn is (series : parallel):
Q14
A parallel plate capacitor of plate area A and separation d has a conducting slab of thickness t inserted between the plates. The new capacitance is:
Q15
The energy density in a region where the electric field is E (in vacuum) is: